Change the email address of the Apple ID. You can’t transfer purchases. You can change the address at appleid.apple.com. Do it while you have access to both addresses.
I would recommend that unless the Apple ID is provided by your employer (I.e. with a device), or you are your employer, everyone use an email address which is theirs rather than @work.com for their Apple ID.
One other possible workaround to keep access to purchases would be to create a new Apple ID and then set the new one up as the head of a family for family sharing. Then invite your work email Apple ID to be a part of the family. Most things purchased under your work Apple ID would then be available to anyone in the family.
I changed apple ids this way about 2 years ago and still have access to most of the app purchases, all the movies, tv shows, music, and iBooks purchases from my old Apple ID.